Dispersion interaction in hydrogen-chain models

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Dispersion interaction in hydrogen-chain models.

We have investigated the dispersion interaction in hydrogen chain models via density functional theory-based symmetry-adapted perturbation theory using the asymptotically corrected PBE0 energy functional. The quasimetallic and the insulating prototype systems were chosen to be hydrogen chains with equally and alternately spaced H(2) units, respectively. The dependence of the dispersion energy o...

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Performance of conventional and dispersion-corrected density-functional theory methods for hydrogen bonding interaction energies.

The approximate CCSD(T)/CBS binding energies for the set of 23 hydrogen-bonded dimers (HB23) of the S66 set reported by Řezáč et al. (J. Chem. Theory Comput. 2011, 7, 2427-2438) were expected to be under-estimated based on the known under-binding tendency of the counterpoise correction combined with small basis sets. In this work, we present binding energies for the HB23 set of dimers obtained ...

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Higher-order Cn dispersion coefficients for hydrogen

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ژورنال

عنوان ژورنال: The Journal of Chemical Physics

سال: 2011

ISSN: 0021-9606,1089-7690

DOI: 10.1063/1.3563596